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Diving Catch
Leap
Very Long Legs
Block
Dodge
Side Step
Is a human made entirely of rubber. He is immune to blunt attacks, bullets and generally incredibly resilient towards damage. He doesn't take injuries from heights or crushing into objects which allows him to use his arms as some sort of slingshot as travel method on difficult terrain.
Luffy has spent the first 2 years of his existance in his mothers womb, resulting in a form of severe dementia. Of course his mother didn't survive the birth.
His father is a known internationally wanted terrorist so he grew up with his grandfather, creating a trauma which in turn resulted in his desire to become a pirate. Important coinfluence was certainly an older man called Shanks, who was a male role model for Luffy and filled the present void as a father figure. Shanks helped Luffy along the way to make poor life decisions having poor charakteristical traits himself and being a pirate.
http://www.youtube.com/watch?v=9LEAQay-HdY