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Rangiku tends to be a slacker who dislikes paperwork and loves to drink. She is not the slightest bit modest about her appearance, frequently referring or complaining about her large breasts in normal casual conversation, much to the embarrassment/amusement of anyone around at the time. She is not above using her considerable feminine charms to get her way, as shown when she tries - albeit unsuccessfully - to bribe Ichigo Kurosaki into letting her stay at his house.
Her easy-going and free-spirited personality makes a sharp contrast to the serious Hitsugaya, but the two seem to be quite close regardless. Rangiku met the young boy prior to him utilizing his power and encouraged him to enter the shinigami academy. As a lieutenant, she is almost constantly by his side and has shown deep loyalty to him on several occasions, even though her laziness frequently annoys him.
While she seems somewhat self-centered, she is sensitive to the feelings of others, evident when she sees the concern Hitsugaya has for Momo Hinamori, the guilt Izuru Kira shares with her when Gin Ichimaru is revealed as a traitor, and when Orihime feels depressed about her role in Ichigo Kurosaki's life. Despite her lackadaisical image, she can be extremely serious when needed and is a capable fighter and strategist, best-shown when she uses clever teasing to manipulate the third Espada's Fraccion into squabbling among themselves and dropped their guard, leaving them open for an attack.
Matsumoto's favorite food is dried persimmon, just like that of Ichimaru. She dislikes bamboo shoots because of their sharp flavor. Her favorite pass-time activities are afternoon napping and Japanese dance. It is also known that she collects kimonos, and grabs every opportunity to get herself treated to sake, she can spend her entire free days drinking. Her favorite "drinking buddies" are Shunsui Kyoraku and Shuhei Hisagi.